81640-25-7

Basic information

• Product Name: 3-(4-Methylphenylsulfonyl)-2-oxa-3-azabicyclo<3.2.1>oct-6-en
• CAS NO: 81640-25-7
• Molecular Weight: 265.333
• Mol File: 81640-25-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-(4-Methylphenylsulfonyl)-2-oxa-3-azabicyclo<3.2.1>oct-6-en(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-Methylphenylsulfonyl)-2-oxa-3-azabicyclo<3.2.1>oct-6-en(81640-25-7)
• EPA Substance Registry System: 3-(4-Methylphenylsulfonyl)-2-oxa-3-azabicyclo<3.2.1>oct-6-en(81640-25-7)

Safety Data

• Hazardous Substances Data: 81640-25-7(Hazardous Substances Data)

Upstream product

• 81640-21-3 2-Benzoyloxy-2-azabicyclo<2.2.1>hept-5-en 
• 6671-85-8 2-azabicyclo[2.2.1]hept-5-ene 
• 81640-22-4 N-hydroxy-2-azabicyclo<2.2.1>hept-5-ene 
• 98-59-9 p-toluenesulfonyl chloride 

Relevant articles and documents

Rearrangement with Oxygen-Insertion in Azabicyclic Hydroxylamine Derivatives

N-Hydroxy-2-azabicyclohept-5-ene (1) is rearranged to the oxaazabicyclic compounds 3,4, and 8 by the reaction with either tosyl or benzoyl chloride.The structure of 3 was proved by X-ray analysis.Experiments with tosyl chloride as well product

SAUERSTOFF-INSERTION BEI DER UMLAGERUNG VON 2-AZA-BICYCLOHEPT-2-EN-DERIVATEN

N-Acyclation of N-hydroxy-2-azabicyclohept-2-ene causes rearrangement to oxa-aza-bicycles (7, 8) by insertion of the hydroxalamine oxygen into the heterocyclic system.The mechanism is elucidated.