81650-63-7Relevant academic research and scientific papers
Iridium-catalyzed allylic alkylations of sodium phenyl selenide
Cui, Ruimin,Guo, Xinwen,Zheng, Shengcai,Zhao, Xiaoming
, p. 2647 - 2651 (2013/01/15)
An iridium-catalyzed allylic substitution of sodium phenyl selenide with unsymmetrical allyl carbonates was accomplished, which produced the linear allyl phenyl selenides in 38%-74% yields. An asymmetric iridium-catalyzed allylation of sodium phenyl selen
PHENYLSELENODESILYLATION OF ALLYLSILANES AND REGIOSPECIFIC TRANSFORMATION OF ALLYLSILANES TO ALLYLIC ALCOHOLS VIA ALLYLSELENIDES
Nishiyama, Hisao,Itagaki, Kazuyoshi,Sakuta, Koji,Itoh, Kenji
, p. 5285 - 5288 (2007/10/02)
Allylsilanes were converted regiospecifically to allylselenides by reaction with phenylselenenyl chloride and subsequent treatment with anhydrous tin(II)chloride or florisil.Oxidative work-up of these allylselenides gave the corresponding allylic alcohols regiospecifically.
