81650-72-8Relevant academic research and scientific papers
Efficient synthesis of vinylcycloalkylphenyl sulfides from DME-activated NaNH2 induced intramolecular dialkylation of allylphenylsulfide
Choppin, Sabine,Gros, Philippe,Fort, Yves
, p. 795 - 801 (2000)
Vinylcycloalkylphenylsulfides have been prepared efficiently by a one- pot intramolecular dialkylation of allylphenylsulfide. The used basic reagent is constituted of a suspension of commercial NaNH2 in 1,2-dimethoxyethane as nonionic activating agent.
Synthesis of cyclic ethers and allylic sulfides by rearrangement of phenylsulfanyl substituted 1,n-diols with toluene-p-sulfonic acid and with toluene-p-sulfonyl chloride
Djakovitch, Laurent,Eames, Jason,Fox, David J.,Sansbury, Francis H.,Warren, Stuart
, p. 2771 - 2782 (2007/10/03)
Rearrangement of a series of l,n-diols (n = 2 to 12), with a PhS-group adjacent to one OH group, under two sets of conditions gives single compounds in excellent yield drawn for four possible classes of products. The effect of the chain length helps in the understanding of the different cyclisation modes and the mechanism of the rearrangements. The Royal Society of Chemistry 1999.
A VERSATILE METHOD FOR ALLYLIC SULFIDE SYNTHESIS
Sato, Tsuneo,Hiramura, Yasuaki,Otera, Junzo,Nozaki, Hitosi
, p. 2821 - 2824 (2007/10/02)
A practical method for synthesizing a variety of allylic sulfides has been developed through Wittig(-Horner) reaction of α-sulfenylated aldehydes which are readily accessible from methoxy(phenylthio)methane.
PHENYLSELENODESILYLATION OF ALLYLSILANES AND REGIOSPECIFIC TRANSFORMATION OF ALLYLSILANES TO ALLYLIC ALCOHOLS VIA ALLYLSELENIDES
Nishiyama, Hisao,Itagaki, Kazuyoshi,Sakuta, Koji,Itoh, Kenji
, p. 5285 - 5288 (2007/10/02)
Allylsilanes were converted regiospecifically to allylselenides by reaction with phenylselenenyl chloride and subsequent treatment with anhydrous tin(II)chloride or florisil.Oxidative work-up of these allylselenides gave the corresponding allylic alcohols regiospecifically.
