81657-07-0

Basic information

• Product Name: diethyl 1,3-adaMantanediacetate
• Synonyms: diethyl 1,3-adaMantanediacetate;Diethyl adamantane-1,3-diacetate;Tricyclo[3.3.1.13,7]decane-1,3-diacetic acid diethyl ester;Diethyl 2,2'-(adaMantane-1,3-diyl)diacetate
• CAS NO: 81657-07-0
• Molecular Formula: C18H28O4
• Molecular Weight: 308.41252
• Mol File: 81657-07-0.mol

Chemical Properties

• Appearance: /
• Density: 1.112±0.06 g/cm3 (20 ºC 760 Torr)
• CAS DataBase Reference: diethyl 1,3-adaMantanediacetate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl 1,3-adaMantanediacetate(81657-07-0)
• EPA Substance Registry System: diethyl 1,3-adaMantanediacetate(81657-07-0)

Safety Data

• Hazardous Substances Data: 81657-07-0(Hazardous Substances Data)

Usage

Uses

Used in Fragrance Industry:
DIETHYL 1,3-ADAMANTANEDIACETATE is used as a fragrance ingredient for its pleasant odor, enhancing the scent profiles of various perfumes and scented products.
Used in Flavoring Industry:
In the flavoring industry, DIETHYL 1,3-ADAMANTANEDIACETATE serves as a flavor enhancer, contributing to the taste profiles of food and beverages.
Used in Pharmaceutical Industry:
DIETHYL 1,3-ADAMANTANEDIACETATE is utilized as an active pharmaceutical ingredient or as a component in the formulation of medications, capitalizing on its pleasant taste to improve patient compliance.
Used as a Solvent:
DIETHYL 1,3-ADAMANTANEDIACETATE functions as a solvent in various chemical processes, facilitating reactions and aiding in the dissolution of other substances.
Used in Organic Chemistry Research:
DIETHYL 1,3-ADAMANTANEDIACETATE is employed as an intermediate in the synthesis of various organic compounds, leveraging its unique reactivity for the development of new chemical entities.
Used in the Synthesis of Intermediates:
Its role as an intermediate highlights its importance in the production of other valuable compounds, contributing to the advancement of organic chemistry and related fields.

Upstream product

• 64-17-5 ethanol 
• 17768-28-4 1,3-adamantane diacetic acid 
• 31898-14-3 1,3-adamantanediacetyl dichloride 

Downstream Products

• 80121-65-9 2-[3-(2-hydroxy-ethyl)-adamantan-1-yl]-ethanol 

Relevant articles and documents

Diamondoid hydrazones and hydrazides: Sterically demanding ligands for Sn/S cluster design

A series of new adamantane and diamantane hydrazides was synthesized and coupled with organo-functionalized Sn/S clusters of the general type [R 1Sn4S6] (R1 = CMe2CH 2COMe) to form diamondoid-decorated Sn/S clusters. The new ligand precursors as well as the resulting hybrid compounds were analyzed by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction, and first insights were gained in the installation of sterically highly demanding and at the same time rigid mono-, di-, and trifunctionalized diamondoid ligands on tetrelchalcogenide cages.

Oxidation of Deactivated Cage Substrates in the System H2SO4–HNO3

Abstract: The kinetics of oxidation of 16 carboxylic acid esters of the adamantaneseries in the systemH2SO4–HNO3have been studied, and the effective rate constants have been determined. Thereaction is described by the pseudo-first-order kinetic equation. The primarykinetic isotope effect has been estimated at 2.9±0.3. The rate-determining stepof the oxidation process is cleavage of the adamantane C–H bond. The presence ofan ethyl group at the bridgehead position increases the reactivity of adamantanesubstrates toward oxidation, whereas methyl, ethoxycarbonyl, andethoxycarbonylmethyl groups reduce the reactivity.

Design and synthesis of new adamantyl-substituted antileishmanial ether phospholipids

A series of new 2-[3-(2-alkyloxy-ethyl)-adamantan-1-yl]-ethoxy substituted ether phospholipids was synthesized and their antileishmanial activity was evaluated against Leishmania infantum amastigotes. The majority of the new analogues were significantly l

A CONVENIENT SYNTHESIS OF 1,3-DIVINYLADAMANTANE

1,3-Divinyladamantane was prepared in 30percent overall yield by LiAlH4 reduction of 1,3-bis(carboxymethyl)adamantane, conversion of the resulting diol to the borate ester, and pyrolysis of the ester in vacuo.

Unsaturated esters of adamantane containing diols and thermo-resistant cross-linked polymers therefrom

Diacrylate and dimethacrylate esters corresponding to the formula STR1 wherein R and R' are hydrogen or methyl and A is either a sigma (?) bond; a (CH2)η radical where η is an interger that may vary from one through four; or phenylene, or an alkyl derivative thereof. The new adamantane containing difunctional olefinic monomers can then be polymerized, or copolymerized with other acrylic type olefinic monomers to produce polymers with unusual physical properties, including unusual hardness, inertness to degradable agents, and resistance to heat.