81694-54-4Relevant academic research and scientific papers
Practical preparation of 2-halomethyl-allyl carboxylates
Sun, Chong-Si,Cheng, Hsiu-Yi,Lin, Yu-Shiang,Hou, Duen-Ren
, p. 435 - 438 (2008/12/22)
An improved, efficient preparation of 2-(halomethyl)allyl carboxylates starting from diethyl bis(hydroxymethyl) malonate and hydrobromic acid is reported. The allylic halogen of 2-(chloromethyl)acrylate and 2-(bromomethyl)acrylate are readily exchanged during esterification.
Regiospecific addition of benzeneselenenyl halide to 1,1-disubstituted olefins
Ho, Pak-Tsun,Kolt, Ralph J.
, p. 663 - 666 (2007/10/02)
The reaction of benzeneselenenyl halide with a variety of 1,1-disubstituted olefins under controlled conditions yields regiospecifically the anti-Markovnikov adducts which have been converted into the synthetically yseful vinyl halides and allyl halides.
