81699-72-1

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 4079-52-1 methoxymethyl phenyl ketone 

Downstream Products

• 108574-64-7 ethyl-2 phenyl-3 methoxy-4 cyclohexene-2 one 
• 108574-63-6 phenyl-3 methoxy-4 cyclohexene-2 one 
• 108574-55-6 methoxy-2 phenyl-1 octanedione-1,5 
• 108574-56-7 methoxy-2 phenyl-1 methyl-2 hexanedione-1,5 
• 108574-54-5 methoxy-2 phenyl-1 hexanedione-1,5 
• 81699-78-7 2-tert-Butoxy-2-methoxy-1-phenyl-ethanone 

Relevant academic research and scientific papers

A NEW METHOD FOR THE DIRECT INTRODUCTION OF ALKOXYL GROUP TO SILYL ENOL ETHER WITH ALKYL HIPOCHLORITE CATALYZED BY PALLADIUM(0)

α-Alkoxyketones and α-ketoacetals are prepared in good yields from silyl enol ethers and alkyl hypochlorites catalyzed by tetrakis(triphenylphosphine)palladium(0).

Reaction des vinylogues d'hemiacetals avec les ethers d'enols β-heterosubstitues : nouvelle synthese et cyclisation de composes δ-dicarbonyles α-heterosubstitues

Reaction of hemiacetal vinylogs 1 in the presence of boron trifluoride etherate with silyl enol ethers 2 or 3 prepared from α-heterosubstituted ketones 7 or 9 yields α-halo δ-dicarbonyl compounds 4 (X = Cl, Br) or α-methoxy δ-dicarbonyl compounds 5.When s