81708-96-5

Basic information

• Product Name: C₁₁H₁₉N
• Synonyms: C₁₁H₁₉N
• CAS NO: 81708-96-5
• Molecular Weight: 165.279
• Mol File: 81708-96-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₉N(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₉N(81708-96-5)
• EPA Substance Registry System: C₁₁H₁₉N(81708-96-5)

Safety Data

• Hazardous Substances Data: 81708-96-5(Hazardous Substances Data)

Upstream product

• 858025-80-6 citral N-methylaldimine 

Downstream Products

• 14505-74-9 α-cyclocitral 
• 432-25-7 2,6,6-trimethylcyclohex-1-enecarbaldehyde 

Relevant articles and documents

Improved synthesis of methyl 3-oxo-2,6,6-trimethylcyclohex-1-ene-1- carboxylate, an A-ring intermediate for (±)strigol

Methyl 3-oxo-2,6,6-trimethylcyclohex-1-ene-1-carboxylate was synthesised over eight steps from the starting material of citral instead of α-ionone. KMnO4, HC(OEt)3 and O2/TEMPO/CuCl were substituted for NaIO4, CH3I and pyridinium chlorochromate, respectively. Every step was simplified and gave a 48% overall yield. The procedure is suitable for large scale production.