817203-48-8Relevant articles and documents
Production method of sulfonium salt compound
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Page/Page column 15, (2009/04/23)
A production method of a sulfonium salt compound represented by the following general formula (1): wherein Ar represents an aromatic compound residue, X represents a halogen atom, which is a substituent on the aromatic compound residue, n represents an integer of from 1 to 7, a plurality of each of Ar, X and n may be the same or different, and Z represents a counteranion other than a halide ion, the method comprising: reacting an aryl halide compound with a compound represented by the following general formula (2) in the presence of a Lewis acid wherein Y1 and Y2 each independently represent a halogen atom, an alkoxy group or an aryloxy group; terminating the reaction by water in an after-treatment step of the reaction; isolating a water layer from the reaction mixture that has been separated into two layers; extraction-treating the water layer by an organic solvent to remove a by-product; adding a compound represented by the following general formula (3) to the extraction-treated water layer to precipitate the sulfonium salt compound represented by the general formula (1) ???????? M-Z?????General Formula (3) wherein Z is as defined above, and M represents a proton or an alkali metal cation; and isolating the precipitated sulfonium salt compound by solid-liquid separation.