81790-68-3Relevant academic research and scientific papers
Palladium-Assisted C-Glycosylation. Addition of Carbanions to Cyclic Enol Ethers
Dunkerton, Lois V.,Serino, Anthony J.
, p. 2812 - 2814 (1982)
Pd(II) effects the regiospecific addition of carbanions to dihydrofuran at the ring oxygen-bearing carbon.A similar regiospecific alkylation of acetoxydihydropyrans catalyzed by Pd(0) is also reported.Initial examples of the stereoselectivity of these reactions are also given.
PALLADIUM(0) ASSISTED SYNTHESIS OF C-GLYCOPYRANOSYL COMPOUNDS
Dunkerton, Lois V.,Euske, Jack M.,Serino, Anthony J.
, p. 89 - 108 (2007/10/02)
Tetrakis(triphenylphosphine)palladium(0) effects the regio- and stereo-selective alkylation of 2-acetoxy-5,6-dihydro-2H-pyrans and 1-S-acetyl-1-thiohex-2-enopyranosides.Use of stabilized carbanions resulted in the formation of alkylated dihydropyrans with
