Palladium-Assisted C-Glycosylation. Addition of Carbanions to Cyclic Enol Ethers

DOI: 10.1021/jo00135a035

Source and publish data:

Journal of Organic Chemistry p. 2812 - 2814 (1982)

Update date:2022-08-05

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Authors:

Dunkerton, Lois V.

Serino, Anthony J.

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Article abstract of DOI:10.1021/jo00135a035

Pd(II) effects the regiospecific addition of carbanions to dihydrofuran at the ring oxygen-bearing carbon.A similar regiospecific alkylation of acetoxydihydropyrans catalyzed by Pd(0) is also reported.Initial examples of the stereoselectivity of these reactions are also given.

Full text of DOI:10.1021/jo00135a035

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