81795-70-2Relevant academic research and scientific papers
Deuterium-induced 13C NMR Nuclear Magnetic Resonance Isotope Shifts and 13C-2H Couplings for Signal Assignments and Determination of Deuteration Site in Cyclooctanone
Milosavljevic, Slobodan,Jeremic, Dragoslav,Mihailovic, Mihailo Lj.,Wehrli, Felix W.
, p. 299 - 300 (1981)
Unambiguous signal assignments in the 13C spectra of monosubstituted cyclooctanones derived from the lead tetraacetate or silver oxide/bromine oxidations of the corresponding 1-monodeutero-alcohols have been obtained from deuterium-induced 13C isotope shifts and geminal and vicinal 13C-2H spin-spin coupling constants.The label in the ketones is shown to be in position 5.
