81805-71-2Relevant academic research and scientific papers
Synthesis of Functionalized Monoaryl-λ3-iodanes through Chemo- and Site-Selective ipso-Substitution Reactions
Komami, Narumi,Matsuoka, Keitaro,Nakano, Ayako,Kojima, Masahiro,Yoshino, Tatsuhiko,Matsunaga, Shigeki
supporting information, p. 1217 - 1220 (2019/01/04)
Monoaryl-λ3-iodanes are potentially attractive arylating agents. They are generally synthesized from aryl iodides via oxidation, which can cause functional group incompatibility, especially when polyfunctionalized derivatives are desired. This work describes the direct synthesis of monoaryl-λ3-iodanes through a chemoselective ipso-substitution reaction of arylgermanes and arylstannanes with iodine tris(trifluoroacetate). The generated iodanes were converted to iodonium ylides or used for further transformations in one pot. The presented method enables the preparation of polyfunctionalized monoaryl-λ3-iodanes.
