81807-64-9Relevant academic research and scientific papers
Surface-mediated solid phase reaction. Part 9. A convenient procedure for aldol reaction of ketene silyl acetals with aldehydes on the solid surface of alumina
Ranu, Brindaban C.,Saha, Manika,Bhar, Sanjay
, p. 3065 - 3077 (1997)
The aldol reaction of ketene silyl acetals with aldehydes proceeds efficiently on the solid surface of alumina impregnated with anhydrous zinc chloride under sonication providing aldol products in high yields and with good stereoselectivity.
Enolboration. 6. Dicyclohexyliodoborane, a Versatile Reagent for the Stereoselective Synthesis of Either Z or E Enolates from Representative Esters
Ganesan, Kumaraperumal,Brown, Herbert C.
, p. 2336 - 2340 (2007/10/02)
A smooth, rapid, quantitative, and highly stereoselective synthesis of either Z or E enolates from representative esters has been achieved with dicyclohexyliodoborane, Chx2BI, in the presence of a suitable tertiary amine, such as triethylamine or N,N-diis
A NEW METHOD FOR THE SYNTHESIS OF β-HYDROXYESTERS BY USING METALLIC TIN
Harada, Taira,Mukaiyama, Teruaki
, p. 161 - 164 (2007/10/02)
Metallic tin or activated metallic tin, prepared by reduction of stannous chloride with lithium aluminum hydride, smoothly reacts with α-haloesters to yield tin enolates, which in turn react with carbonyl compounds under mild conditions to give, after hydrolysis, β-hydroxyesters in high yields.
