81810-74-4

Basic information

• Product Name: Ethanone, 1-(4,5-dihydro-2,4,5-trimethyl-5-oxazolyl)- (9CI)
• Synonyms: Ethanone, 1-(4,5-dihydro-2,4,5-trimethyl-5-oxazolyl)- (9CI)
• CAS NO: 81810-74-4
• Molecular Formula: C₈H₁₃NO₂
• Molecular Weight: 155.19432
• Product Categories: ACETYLGROUP
• Mol File: 81810-74-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(4,5-dihydro-2,4,5-trimethyl-5-oxazolyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4,5-dihydro-2,4,5-trimethyl-5-oxazolyl)- (9CI)(81810-74-4)
• EPA Substance Registry System: Ethanone, 1-(4,5-dihydro-2,4,5-trimethyl-5-oxazolyl)- (9CI)(81810-74-4)

Safety Data

• Hazardous Substances Data: 81810-74-4(Hazardous Substances Data)

Upstream product

• 4510-37-6 trans-1-(2,3-dimethyloxiranyl)-ethanone 
• 75-05-8 acetonitrile 
• 4587-00-2 2-acetyl-2-methyloxirane 
• 83750-07-6 4-chloro-3-hydroxy-3-methylbutan-2-one 

Downstream Products

• 83750-19-0 Acetic acid (E)-1-(1-amino-ethyl)-1-methyl-2-oxo-4-p-tolyl-but-3-enyl ester; hydrochloride 
• 83750-25-8 N-((E)-2-Hydroxy-1,2-dimethyl-3-oxo-5-p-tolyl-pent-4-enyl)-acetamide 
• 83750-13-4 (E)-3-(4-Bromo-phenyl)-1-(2,4,5-trimethyl-4,5-dihydro-oxazol-5-yl)-propenone 
• 81810-79-9 (E)-3-p-Tolyl-1-(2,4,5-trimethyl-4,5-dihydro-oxazol-5-yl)-propenone 

Relevant articles and documents

REACTION OF ACETYLOXIRANES WITH ACETONITRILE

2-Acetyloxiranes react with acetonitrile in the presence of equimolar amounts of Lewis acids.It was established that the use of boron trifluoride etherate or sulfuric acid as the catalyst leads to 2,7- and 3,6-diepoxy-1,5-dioxocanes, the use of aluminum trichloride, as well as stannic chloride, leads to the corresponding chlorohydrins, while the use of gaseous boron trifluoride leads to 2-oxazolines in satisfactory yields.It is shown that the reaction is regio- and stereospecific and that the resulting substituted 2-methyl-5-acetyl-2-oxazolines have a cis configuration.