81832-88-4Relevant academic research and scientific papers
Reduction-Oxidation Properties of Organotransition-metal Complexes. Part13. Cationic Iron(II) Carbonyls via the Radical Coupling, and Substitution Reactions of (1+): Synthetic and Electron Spin Resonance Spectroscopic Studies
Baker, Paul K.,Broadley, Karen,Connelly, Neil G.
, p. 471 - 476 (2007/10/02)
The radical cation (l+) undergoes oxidative-substitution reactions with the diamagnetic ligands S2CPPh3 and (1-) to give cis,trans-z (R=PPh3, Z=2; R=NMe2, Z=1): the dithiocarbamato-complex is also prepared from Me2NC(S)SSC(S)NMe2.Radical-radical coupling occurs between (1) and NO or NO2 to give (1+) and mer, trans-(1+) respectively.On thermolysis, the nitro-complex yields CO2 and the nitrosyl derivative via cis,trans-(l+) with t-BuNO, and the formation of paramagnetic complexes with 1,2-diketones, have been studied by e.s.r. spectroscopy; cis,trans-(l+), from 3,4,5,6-tetrachloro-p-benzoquinone, has been isolated and fully characterised.
