81835-18-9

Upstream product

• 81823-15-6 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-5-C-(p-tolylsulfonylhydrazino)-α-D-xylo-hexofuranose 
• 81823-13-4 3,6-Di-O-benzyl-1,2-O-isopropylidene-α-D-xylo-hexofuranos-5-ulose(E,Z)-5-(p-tolylsulfonyl)hydrazone 
• 7162-15-4 methyl phenylphosphinate 
• 81823-16-7 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-α-D-xylo-hexofuranose 

Downstream Products

• 81823-18-9 1,2,4-tri-O-acetyl-3,6-di-O-benzyl-5-deoxy-5-C-(phenylphosphinyl)-β-D-glucopyranose 

Relevant academic research and scientific papers

SYNTHESIS OF 1,2,4-TRI-O-ACETYL-3,6-DI-O-BENZYL-5-DEOXY-5-C--β-D-GLUCOPYRANOSE: THE FIRST gluco TYPE OF HEXOPYRANOSE DERIVATIVE HAVING PHOSPHORUS IN THE HEMIACETAL RING

Oxidation of 3,6-di-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose with pyridinium chlorochromate in the presence of molecular sieves, followed by conversion into the p-tolylsulfonylhydrazone, addition of methyl phenylphosphinate, and reduction with sodi