81844-52-2Relevant academic research and scientific papers
Role of Metal Ions in Reactions of dl-Camphorquinone with Monoamines
Mukhedkar, V. A.,Rajgolkar, R. L.,Mukhedkar, A. J.
, p. 295 - 299 (2007/10/02)
The condensation of monoamines with dl-camphorquinone in the presence of metal ions (Co2+, Ni2+, Cu2+) gave two classes of metal complexes.The reactions leading to Class 1 complexes gave monoimines with the imino group at C(2) and C(3) positions.The reactions leading to Class II complexes gave monoimines with the imino group at C(3) position only, similar to that obtained by the direct condensation reaction in the absence of a metal ion.A diimine is also obtained in a reaction involving copper(II) complexes of Class I.
