819073-84-2Relevant academic research and scientific papers
Two concise enantioselective total syntheses of (-)-glabrescol implicate alternative biosynthetic pathways starting from squalene
Yang, Peng,Li, Pei-Fang,Qu, Jin,Tang, Liang-Fu
supporting information; experimental part, p. 3932 - 3935 (2012/10/08)
The C2-symmetric (-)-glabrescol was synthesized in two steps from (10S,11R)-dihydroxy-10,11-dihydrosqualene or squalene with 50% or 10% overall yields, respectively. These highly efficient and biomimetic syntheses employed a base-promoted middl
Arylacetic acid derivatization of 2,3- and internal erythro-squalene diols. Separation and absolute configuration determination
Abad, José-Luis,Camps, Francisco
, p. 11519 - 11525 (2007/10/03)
We have studied a new approach for the resolution and absolute configuration determination of the enantiomers of squalene diols as intermediate precursors in the chemical synthesis of different squalene oxides (SOs); (3R)- and (3S)-2,3-SO, (6R,7R)- and (6
