81969-75-7

Upstream product

• 81939-81-3 trans-3,5-dimethyl-3-hydroxycyclohex-1-en-4-one 
• 81939-75-5 5-methyl-6-(trimethylsiloxy)cyclohex-2-en-1-one 

Downstream Products

• 81939-86-8 trans,cis-3,5-dimethyl-1-phenylthio-trans,cis,cis-2,3,4-trihydroxycyclohexane 3,4-acetonide 
• 81939-88-0 cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylthio)cyclohexane 3,4-acetonide 
• 81939-92-6 cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-1-mercapto-trans-2-(phenylsulfinyl)cyclohexane 3,4-acetonide 
• 81939-89-1 cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)-1-<(trifluoroacetyl)thio>cyclohexane 3,4-acetonide 
• 81939-90-4 Trifluoro-thioacetic acid S-((3aR,4R,5R,7R,7aR)-4-benzenesulfinyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-5-yl) ester 
• 81939-83-5 3-[2-((3aR,4R,5R,7R,7aR)-4-Benzenesulfinyl-2,2,3a,7-tetramethyl-hexahydro-benzo[1,3]dioxol-5-ylsulfanyl)-ethoxy]-cyclopent-2-enone 
• 81939-87-9 1-chloro-cis,trans-3,5-dimethyl-trans,trans-3,4-dihydroxy-trans-2-(phenylthio)cyclohexane 3,4-acetonide 
• 81939-81-3 trans-3,5-dimethyl-3-hydroxycyclohex-1-en-4-one 

Relevant academic research and scientific papers

Cytochalasin Support Studies. The C14-C19 Subunit of Cytochalasin C. Intramolecular 2 + 2 Photochemical Cycloaddition of Vinyl Sulfones

An intramolecular 2? + 2? photochemical cycloaddition between a six-membered ring vinyl sulfone and a five-membered ring vinylogous ester is described.The process occurs with moderate regiospecificity, the direction being controlled by a cis-acetonide moiety on the six-membered ring.Attempts to fragment the β-alkoxy sulfone adduct to trigger a DeMayo ring expansion were unsuccessful.