819798-40-8Relevant academic research and scientific papers
Synthesis and biological evaluation of the Forssman antigen pentasaccharide and derivatives by a one-pot glycosylation procedure
Tanaka, Hiroshi,Takeuchi, Ryota,Jimbo, Mitsuru,Kuniya, Nami,Takahashi, Takashi
, p. 3177 - 3187 (2013/03/28)
The synthesis and biological evaluation of the Forssman antigen pentasaccharide and derivatives thereof by using a one-pot glycosylation and polymer-assisted deprotection is described. The Forssman antigen pentasaccharide, composed of GalNAcα(1,3)GalNAcβ(
Synthesis of the repeating unit of the lipoteichoic acid of Streptococcus pneumoniae
Pedersen, Christian Marcus,Figueroa-Perez, Ignacio,Ulmer, Artur J.,Z?hringer, Ulrich,Schmidt, Richard R.
experimental part, p. 1052 - 1061 (2012/02/14)
The lipoteichoic acid repeating unit of Streptococcus pneumoniae is a complex pseudopentasaccharide (3). It consists of one ribitol-phosphate, one 2-acetamino-4-amino-2,4,6-trideoxy-galactose, one glucose and two galactosamine residues each differently li
Configurations and conformations of glycosyl sulfoxides
Liang, Hong,MacKay, Micheline,Grindley, T. Bruce,Robertson, Katherine N.,Cameron, T. Stanley
, p. 1154 - 1174 (2011/01/08)
X-ray crystallographic studies of two axial glycosyl sulfoxides having RS configurations (derivatives of phenyl 2-azido-2-deoxy-1-thio - d-galactopyranoside S-oxide) show that they adopt anti conformations in the solid state, in contrast to pre
METHOD OF SYNTHESIZING SUGAR CHAIN
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Page/Page column 32-33, (2010/11/08)
An object of the present invention is to provide a method for efficiently chemically synthesizing biomolecules including a nucleotide (nucleic acid), a peptide (protein), or a sugar chain, as representative examples. The present invention provides a metho
Efficient synthesis of core 2 class glycosyl amino acids by one-pot glycosylation approach
Tanaka, Hiroshi,Adachi, Masaatsu,Takahashi, Takashi
, p. 1433 - 1436 (2007/10/03)
We describe the one-pot synthesis of core 2 class branched oligosaccharides initiated by chemo-selective glycosylation of silyl ether. Glycosylation of 6-O-silyl-4-benzyl-2-azido-thiogalactoside with glycosyl fluoride provided selectively 6-glycosylated thioglycoside without both O-glycosylation at the 3 position and S-glycosylation. Subsequent coupling of galactosyl fluoride and amino acids afforded the protected branched oligosaccharides in good yields.
