819865-99-1Relevant articles and documents
A tandem nucleophilic addition, defluorination and destannylation. Stereospecific synthesis of trifluoromethylated alkyl and aryl vinyl ethers
Shen, Yanchang,Wang, Guoping
, p. 2637 - 2640 (2007/10/03)
A novel tandem reaction, including nucleophilic addition, defluorination and destannylation reactions, has been found and its application to the stereospecific synthesis of trifluoromethylated alkyl- and aryl vinyl ethers with exclusive formation of E-isomers in 73-96% yields is reported. An Ad N-E mechanism for the tandem reaction leading to alkyl- and aryl vinyl ethers is proposed.