820243-52-5Relevant academic research and scientific papers
Expedient total syntheses of rhein and diacerhein via fries rearrangement
Tisserand, Steve,Baati, Rachid,Nicolas, Marc,Mioskowski, Charles
, p. 8982 - 8983 (2004)
Short and practical total syntheses of rhein (1) and diacerhein (2) have been achieved via a Fries rearrangement and bis-carbonylation strategy followed by cyclization in molten salt, starting from dibromoester 7.
