Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)-

Base Information

Chemical Name:Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)-
CAS No.:820243-52-5
Molecular Formula:C13H8Br2O3
Molecular Weight:372.013
Hs Code.:
DSSTox Substance ID:DTXSID20459273
Nikkaji Number:J2.131.157J

Synonyms:820243-52-5;Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)-;DTXSID20459273;2,2'-Dihydroxy-4,6-dibromobenzophenone

Suppliers and Price of Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)-

Chemical Property:

XLogP3:4.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:371.88197
Heavy Atom Count:18
Complexity:311

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C(=C1)C(=O)C2=C(C=C(C=C2Br)Br)O)O

Technology Process of Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)-

There total 1 articles about Methanone, (2,4-dibromo-6-hydroxyphenyl)(2-hydroxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 820243-53-6
anisic acid 3,5-dibromophenyl ester

: 2-hydroxy-benzoic acid 3,5-dibromo-phenyl ester

: 820243-52-5
(2,4-dibromo-6-hydroxyphenyl)-(2-hydroxyphenyl)methanone

: 626-41-5
3,5-dibromophenol

Guidance literature:: With zirconium(IV) chloride; In chlorobenzene; at 160 ℃; for 3h;
DOI:10.1021/jo049228l

Reference yield: 87.0%

: 820243-52-5
(2,4-dibromo-6-hydroxyphenyl)-(2-hydroxyphenyl)methanone

: 100-39-0
benzyl bromide

: 820243-54-7
(2-benzyloxy-4,6-dibromophenyl)-(2-benzyloxyphenyl)methanone

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 12h;
DOI:10.1021/jo049228l

Reference yield:

: 820243-52-5
(2,4-dibromo-6-hydroxyphenyl)-(2-hydroxyphenyl)methanone

: 478-43-3
1,8-dihydroxy-3-carboxy-anthraquinone

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / K₂CO₃ / dimethylformamide / 12 h / 80 °C

2: 92 percent / Et₃N; (dppf)PdCl₂; dppf / dimethylformamide / 18 h / 80 °C / 750.06 Torr

3: KOH / methanol / 48 h / 60 °C

4: 414 mg / H₂ / Pd/C / ethanol / 12 h / 20 °C / 750.06 Torr

5: 50 percent / AlCl₃; NaCl / 2 h / 150 °C

With 1,1'-bis-(diphenylphosphino)ferrocene; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium hydroxide; aluminium trichloride; hydrogen; potassium carbonate; triethylamine; sodium chloride; palladium on activated charcoal; In methanol; ethanol; N,N-dimethyl-formamide;
DOI:10.1021/jo049228l