82026-21-9

Upstream product

• 82026-20-8 6-Hexa-4,5-dienyl-1,4-dioxa-spiro[4.5]decane 
• 10424-93-8 N'-cyclohexylidene-N,N-dimethyl-hydrazine 
• 69543-14-2 6-iodo-hexa-1,2-diene 
• 60857-51-4 6-bromohexa-1,2-diene 
• 62547-87-9 3-(1,4-dioxaspiro[4,5]dec-6-yl)propan-1-ol 
• 82026-18-4 2-(1,4-dioxaspiro<4.5>decan-6-yl)propyl methanesulfonate 
• 82026-19-5 6-(3-iodopropyl)-1,4-dioxaspiro<4.5>decane 

Downstream Products

• 82026-22-0 2-(4,5-hexadienyl)cyclohex-1-en-1-yl acetate 
• 92747-18-7 4-vinyloctahydronaphthalen-4a-ol 
• 771574-42-6 2-(4,5-hexadienyl)-2-iodo-1-cyclocyclohexanone 
• 82026-17-3 2-(4,5-hexadienyl)-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Ketyl-allene cyclizations promoted by samarium(II) iodide

(Chemical Equation Presented) Samarium(II) iodide has proven to be an effective reagent for intramolecular reductive coupling Sreactions. Previous investigations of intramolecular ketyl-olefin coupling reactions provided carbocycles in excellent yield and good diastereoselectivity. This method has been extended to ketyl cyclizations with allenes. Substrates leading to both carbocycles and heterocycles in a selective manner are explored.

Photoinduced atom-transfer cyclization of α-iodocycloalkanones bearing an allenyl side chain

(Chemical Equation Presented) Irradiation of α-iodocycloalkanones bearing an allenyl side chain with a sunlamp effected atom-transfer cyclization to give cyclized products in good yield. A mechanism, involving radical atom-transfer cyclization accompanied

Intramolecular Photoaddition of Terminal Allenes to Conjugated Cyclohexenones

Terminal allenes linked to cyclohexenones by hydrocarbon chains were synthesized and irradiated with UV ligth.It was found that cycloaddition occurs regiospecifically in high yield.The adducts were oxidized by ozone to 1,3-diketones which underwen