82026-21-9

Basic information

• Product Name: Cyclohexanone, 2-(4,5-hexadienyl)-
• CAS NO: 82026-21-9
• Molecular Formula: C12H18O
• Molecular Weight: 178.274
• Mol File: 82026-21-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-(4,5-hexadienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-(4,5-hexadienyl)-(82026-21-9)
• EPA Substance Registry System: Cyclohexanone, 2-(4,5-hexadienyl)-(82026-21-9)

Safety Data

• Hazardous Substances Data: 82026-21-9(Hazardous Substances Data)

Upstream product

• 10424-93-8 N'-cyclohexylidene-N,N-dimethyl-hydrazine 
• 62547-87-9 3-(1,4-dioxaspiro[4,5]dec-6-yl)propan-1-ol 
• 82026-18-4 2-(1,4-dioxaspiro<4.5>decan-6-yl)propyl methanesulfonate 
• 82026-19-5 6-(3-iodopropyl)-1,4-dioxaspiro<4.5>decane 
• 60857-51-4 6-bromohexa-1,2-diene 
• 69543-14-2 6-iodo-hexa-1,2-diene 
• 82026-20-8 6-Hexa-4,5-dienyl-1,4-dioxa-spiro[4.5]decane 

Downstream Products

• 82026-17-3 2-(4,5-hexadienyl)-2-cyclohexen-1-one 
• 771574-42-6 2-(4,5-hexadienyl)-2-iodo-1-cyclocyclohexanone 
• 92747-18-7 4-vinyloctahydronaphthalen-4a-ol 
• 82026-22-0 2-(4,5-hexadienyl)cyclohex-1-en-1-yl acetate 

Relevant articles and documents

Ketyl-allene cyclizations promoted by samarium(II) iodide

(Chemical Equation Presented) Samarium(II) iodide has proven to be an effective reagent for intramolecular reductive coupling Sreactions. Previous investigations of intramolecular ketyl-olefin coupling reactions provided carbocycles in excellent yield and good diastereoselectivity. This method has been extended to ketyl cyclizations with allenes. Substrates leading to both carbocycles and heterocycles in a selective manner are explored.

Intramolecular Photoaddition of Terminal Allenes to Conjugated Cyclohexenones

Terminal allenes linked to cyclohexenones by hydrocarbon chains were synthesized and irradiated with UV ligth.It was found that cycloaddition occurs regiospecifically in high yield.The adducts were oxidized by ozone to 1,3-diketones which underwen