82064-90-2Relevant academic research and scientific papers
Kinetic Applications of Electron Paramagnetic Resonance Spectroscopy. 38. Rearrangement of β-(Acyloxy)alkyl and β-(benzoyloxy)alkyl Radicals
Barclay, L. R. C.,Griller, D.,Ingold, K. U.
, p. 4399 - 4403 (2007/10/02)
Rate constants for the free-radical rearrangement, RC(O)OCMe2CH2* --> RC(O)OCH2CMe2*, and for the ring-opening reaction, , have been measured by kinetic EPR spectroscopy.In hydrocarbon solvents at 75 deg C with R = methyl and phenyl, the 1,2-acy
