82066-91-9Relevant academic research and scientific papers
FONCTIONNALISATION BENZYLIQUE EN SERIE ARENE CHROME TRICARBONYLE. CONTROLE ELECTRONIQUE DE LA REGIOSPECIFICITE DE LA REACTION
Brocard, J.,Lebibi, J.
, p. 295 - 306 (2007/10/02)
The regiospecificity of the benzylic functional group of arenetricarbonylchromium cannot be explained by preferential attack at the carbon which is eclipsed by the chromium-carbonyl bond.Electronic effects in directing the regiospecificity of benzylic att
Benzylic Functionalization of Arene(tricarbonyl)chromium Complexes
Brocard, Jacques,Lebibi, Jacques,Couturier, Daniel
, p. 1264 - 1265 (2007/10/02)
The complexation of a Cr(CO)3 unit to an aromatic hydrocarbon enhances the benzylic position towards attack by base and the resulting carbanion reacts with carbonyl compounds to produce a complexed alcohol; this reaction may be used to functionalize the benzylic position of an aromatic hydrocarbon.
