82066-92-0

Upstream product

• 1081-75-0 1,3-diphenylpropane 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 108319-36-4 (1,3-diphenylpropane)bis(tricarbonylchromium) 
• 1076-43-3 benzene-d6 
• 2206-27-1 dimethylsulfoxide-d6 

Downstream Products

• 697302-50-4 (benzene)tricarbonylchromium 
• 108295-90-5 (C₆H₅C⁽²⁾H₂CH₂CH₂C₆H₅)Cr(CO)3 
• 63408-42-4 1,1-dideuterio-1,3-diphenylpropane 
• 82081-10-5 (C₆H₅C(CH₂OH)2(CH₂)2C₆H₅)Cr(CO)3 
• 113031-47-3 (1-(4'-acetylphenyl)-3-phenylpropane)tricarbonylchromium 
• 113031-48-4 (1-(4''-acetylphenyl)-3-phenylpropane)tricarbonylchromium 

Relevant academic research and scientific papers

Neighboring Group Participation in Organometallic Chemistry: Internal Exchange in (Diarylalkane)tricarbonylchromium Complexes

The rates of internal and external exchange of (diarylalkane)tricarbonylchromium complexes in benzene/cyclohexane mixtures have been determined.Neighbouring group participation is demonstrated in all complexes and follows an order with respect to ring siz

Neighboring group participation in organometallic chemistry: Anchimeric assistance in catalyzed arene exchange reactions of (diarylalkane)tricarbonylchromium complexes

Nucleophilic catalysis of the migration of a tricarbonylchromium group from one ring to the other in diarylalkane tricarbonyl derivatives has been observed and compared with catalysis of external exchange. Internal catalysis by a neighboring tricarbonylchromium is also being reported. These results demonstrate the intermediacy of a chromium complex having three carbonyl groups, ketone, and two η2-bound arenes. The consequences of this result for metal exchange reactions are discussed.

Electrophilic Substitution in (Arene)tricarbonylchromium Complexes. Part 1.

The Friedel-Crafts acetylation of several (arene)tricarbonylchromium complexes have been investigated.From the results it is concluded that the tricarbonylchromium group deactivates to a small extent towards electrophilic substitution the ring to which it is attached.In the case of tricarbonyl(diphenylmethane)chromium (1; n=1), however, attack occurred on both rings to about an equal extent, possible explanations for this unexpected behaviour are advanced.