82084-09-1

Basic information

• Product Name: (2-Ethyl-3-methyl-cyclopent-1-enyl)-trimethyl-silane
• CAS NO: 82084-09-1
• Molecular Weight: 182.381
• Mol File: 82084-09-1.mol

Chemical Properties

• CAS DataBase Reference: (2-Ethyl-3-methyl-cyclopent-1-enyl)-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Ethyl-3-methyl-cyclopent-1-enyl)-trimethyl-silane(82084-09-1)
• EPA Substance Registry System: (2-Ethyl-3-methyl-cyclopent-1-enyl)-trimethyl-silane(82084-09-1)

Safety Data

• Hazardous Substances Data: 82084-09-1(Hazardous Substances Data)

Upstream product

• 82084-06-8 (E)-3-(1-trimethylsilylcyclopropyl)pentene 
• 31469-29-1 (1'-(trimethylsilyl)cyclopropyl)carboxylic acid 
• 74379-74-1 1-(phenylthio)-1-(trimethylsilyl)cyclopropane 
• 96-22-0 pentan-3-one 
• 82195-52-6 3-hydroxy-3-ethyl-2-(trimethylsilyl)-1-pentene 
• 86486-88-6 1-bromo-1-(1-trimethylsilyl)cyclopropane 

Relevant articles and documents

SILICON IN ORGANIC SYNTHESIS. 14. FIVE RING ANNULATION PROCESSES BASED UPON THERMAL REARRANGEMENT OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES

Pyrolysis of (1-trimethylsilylcyclopropyl)ethylenes affords silyl substituted cyclopentenes in high yield.Subsequent reaction of these products with varied electrophiles forms the basis of a new and versatile five-ring annulation sequence.

SILICON IN ORGANIC SYNTHESIS-17 CYCLOPENTANNULATION BY THERMOLYSIS OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES-THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION

Several alternatives for preparing (1-trimethylsilylcyclopropyl)ethylenes have been examined.Although 1-lithio-1-(trimethylsilyl)ethylene does add satisfactorily to carbonyl compounds and the subsequent Simmons-Smith cyclopropanation provides the desired