74379-74-1Relevant academic research and scientific papers
A General Procedure for Preparing α-Lithiosilanes. Generalization of the Peterson Olefination
Cohen, Theodore,Sherbine, James P.,Matz, James R.,Hutchins, Robert R.,McHenry, Barry M.,Willey, Paul R.
, p. 3245 - 3252 (2007/10/02)
A particularly convenient method for the preparation of α-lithiosilanes consists of the reductive lithiation of diphenyl thioacetals or thioketals with lithium 1-(dimethylamino)naphthalenide, treatment of the resulting anion with trimethylsilyl chloride,
SILICON IN ORGANIC SYNTHESIS-17 CYCLOPENTANNULATION BY THERMOLYSIS OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES-THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION
Paquette, Leo A.,Wells, Gregory J.,Horn, Keith A.,Yan, Tu-Hsin
, p. 913 - 924 (2007/10/02)
Several alternatives for preparing (1-trimethylsilylcyclopropyl)ethylenes have been examined.Although 1-lithio-1-(trimethylsilyl)ethylene does add satisfactorily to carbonyl compounds and the subsequent Simmons-Smith cyclopropanation provides the desired
SILICON IN ORGANIC SYNTHESIS. 13. THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION AND ITS FORMAL EQUIVALENT
Paquette, Leo A.,Horn, Keith A.,Wells, Gregory J.
, p. 259 - 262 (2007/10/02)
Reaction of lithio 1-trimethylsilylcyclopropane or its formal equivalent with carbonyl compounds leads to carbinols which dehydrate without rearrangement.Other attempts to induce ring expansion of the silicon substituted three-membered ring by i
