82085-93-6Relevant academic research and scientific papers
Alkyl-and arylsulfanyl-substituted unsaturated carbonyl compounds
Kondrashov, Evgeniy V.,Romanov, Alexey R.,Ushakov, Igor A.,Rulev, Alexander Yu.
, p. 18 - 33 (2017)
A method for the synthesis of captodative sulfanyl enals, enones and enoates via nucleophilic vinylic substitution of corresponding halogen-bearing derivatives has been developed. The one-pot treatment of the haloenoates, haloenones or haloenals with thiols in the presence of organic base leads either to vicinal dithiosubstituted carbonyl-bearing compound or captodative systems with good to excellent yield. The major reaction direction strongly depends on the type of base used.
ADDITION OF THIOLS TO DERIVATIVES OF PHENYLPROPYNOIC ACID
Rasteikene, L. P.,Vidugirene, V. I.,Talaikite, Z. A.,Lukoshyavichyute, N. M.
, p. 647 - 651 (2007/10/02)
The reaction of thiophenol and benzyl hydrosulfide with phenylpropynoic acid, its methyl ester, and its anilide was investigated.The addition of thiophenol takes place regioselectively.Under the conditions of a radical reaction derivatives of 2-phenylthio
