24127-62-6

Basic information

• Product Name: 2-Propenoic acid, 2-bromo-3-phenyl-, methyl ester
• CAS NO: 24127-62-6
• Molecular Formula: C10H9BrO2
• Molecular Weight: 241.084
• Mol File: 24127-62-6.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-bromo-3-phenyl-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-bromo-3-phenyl-, methyl ester(24127-62-6)
• EPA Substance Registry System: 2-Propenoic acid, 2-bromo-3-phenyl-, methyl ester(24127-62-6)

Safety Data

• Hazardous Substances Data: 24127-62-6(Hazardous Substances Data)

Upstream product

• 21770-48-9 methyl 2,3-dibromo-3-phenylpropanoate 
• 103-26-4 Methyl cinnamate 
• 100-52-7 benzaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 287481-44-1 methyl 2-(bis(2,2,2-trifluoroethoxy)phosphoryl)-2-bromoacetate 
• 52742-04-8 methyl threo-3-acetoxy-2-bromo-3-phenylpropanoate 
• 52742-04-8 methyl erythro-3-acetoxy-2-bromo-3-phenylpropanoate 
• 52742-04-8 (2R,3S)-3-Acetoxy-2-bromo-3-phenyl-propionic acid methyl ester 
• 52742-04-8 (±)-erythro-methyl-2-bromo-3-(acetoxy)-3-phenylpropanoate 
• 21770-48-9 methyl 2,3-dibromo-3-phenylpropionate 
• 21770-48-9 rac-(R,S)-methyl 2,3-dibromo-3-phenylpropanoate 
• 13504-77-3 methyl 2-bromo-2-(triphenylphosphanylidene)acetate 
• 140-10-3 (E)-3-phenylacrylic acid 
• 74-88-4 methyl iodide 

Downstream Products

• 7029-82-5 3-phenyl-2,3-dipiperidino-propionic acid methyl ester 
• 24127-62-6 methyl 2-bromo-3-phenylacrylate 
• 133377-41-0 methyl (E)-3-phenyl-2-(trifluoromethyl)prop-2-enoate 
• 35016-63-8 (S)-2-bromo-3-phenylpropionic acid 
• 124916-61-6 (S)-2-bromo-3-penylpropanoic acid methyl ester 
• 55836-65-2 (Z)-methyl 3-phenylacrylate-2-d 
• 55836-65-2 methyl (α-deuterio)cinnamate 
• 70288-60-7 methyl 2-bromo-3-phenylpropionate 
• 5556-23-0 3-Hydroxy-5-phenyl-thiophen-2-carbonsaeure-methylester 
• 50413-11-1 5-phenyl-3(2H)-thiophenone 
• 82085-93-6 methyl (E)-3-phenyl-3-(benzylsulfanyl)prop-2-enoate 
• 91735-92-1 methyl (Z)-3-phenyl-3-(benzylsulfanyl)prop-2-enoate 

Relevant articles and documents

Visible light-mediated metal-free double bond deuteration of substituted phenylalkenes

Various bromophenylalkenes were reductively photodebrominated by using 1,3-dimethyl-2-phenyl-1H-benzo-[d]imidazoline (DMBI) and 9,10-dicyanoanthracene. With deuterated DMBI analogs (the most effective was DMBI-d11), satisfactory to excellent isotopic yields were obtained. DMBI-d11 could also be regenerated from the reaction mixtures with a recovery rate of up to 50%. The combination of the photodebromination reaction with conventional methods for bromoalkene synthesis enables sequential monodeuteration of a double bond without the necessity of a metal catalyst. This journal is

Ru-catalyzed highly chemo- and enantioselective hydrogenation of γ-halo-γ,δ-unsaturated-β-keto esters under neutral conditions

Finely-tuned ruthenium-catalyzed highly chemoselective and enantioselective hydrogenation of γ-halo-γ,δ-unsaturated-β-keto esters at the carbonyl group was achieved under neutral reaction conditions (ee up to 97%). Both olefin and alkenyl halogen moieties, which are labile under hydrogenation conditions, remained untouched during the reaction.

Biocatalyzed enantioselective reduction of activated C=C bonds: Synthesis of enantiomerically enriched α-halo-β-arylpropionic acids

The enantioselective biocatalyzed reduction of the C=C bond of some (Z)-methyl α-halo-β-arylacrylates was investigated. The reaction was performed by baker's yeast fermentation and Old Yellow Enzymes 1-3 mediated biotransformations. The final products wer