82159-74-8Relevant academic research and scientific papers
SYNTHESIS OF TWO ENANTIOMERIC TETRASUBSTITUTED CYCLOHEXANONES FROM 6-DEOXYHEX-5-ENOPYRANOSIDE DERIVATIVES
Machado, Antonio Salustiano,Olesker, Alain,Lukacs, Gabor
, p. 231 - 240 (2007/10/02)
The conversion of various 6-deoxyhex-5-enopyranoside derivatives in the presence of a catalytic amount of mercury(II) sulfate into chiral cyclohexanones has been studied.Under the experimental conditions used, the stereochemistry at position 5 of the tetr
STEREOSELETIVITIES IN THE REACTIONS OF α-D-HEXOPYRANOSID-4-ULOSES WITH DIAZOMETHANE
Sato, Ken-Ichi,Yoshimura, Juji
, p. 221 - 238 (2007/10/02)
The stetreoselectivities in the reactions of diazomethane with various α-D-hexopyranosid-4-uloses are compared with those in Grignard reactions.The results support the hypothesis that the stereoselectivity of the diazomethane reaction is mainly controlled
