95640-26-9

Upstream product

• 82159-74-8 methyl 4-O-benzoyl-6-bromo-6-deoxy-2,3-di-O-methyl-α-D-altropyranoside 
• 6748-99-8 methyl 4,6-O-benzylidene-2,3-di-O-methyl-α-D-altropyranoside 
• 56543-17-0 methyl 4-O-benzoyl-6-bromo-6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside 

Downstream Products

• 95640-27-0 2L-2,3/4,5-2-benzoyloxy-5-hydroxy-3,4-dimethoxycyclohexanone 
• 95640-28-1 2L-2,3/4-2-benzoyloxy-3,4-dimethoxycyclohex-5-enone 
• 1384974-87-1 1,6-anhydro-2,3-di-O-methyl-4-O-benzoyl-5-C-hydroxy-β-L-idopyranose 

Relevant academic research and scientific papers

Formation of septanoses from hexopyranosides via 5,6-exo-glycals

Methyl d-hexo-5-ulosides are obtained in high yield by dihydroxylation of 5,6-exo-glucal compounds. The bicyclic structure (1,6-anhydropyrano-5-ulose) of the products is adopted in solution and in solid state in a 4C 1 conformation.

Syntheses of 6-Deoxyhex-5-enopyranosides from 6-Bromo-6-deoxy- or 6-O-p-Tolylsulfonylhexopyranosides by the Use of DBU in DMSO

Various kinds of nonbranched and methyl-branched 6-deoxyhex-5-enopyranoside derivatives were prepared from 6-bromo-6-deoxy or 6-O-p-tolylsulfonylhexopyranoside in a one-pot procedure by a successive treatment with iodide anion and 1,8-diazabicyclou

Highly Selective Metal-Graphite-Induced Reductions of Deoxy Halo Sugars

To explore the applicability of highly active metal-graphite reducing agents to polyfunctional compounds a variety of suitably protected chloro-, bromodeoxy-, and deoxyiodohexopyranosides and hexofuranoses were each treated with potassium-graphite laminat

Convenient Synthesis of Hex-5-enopyranosides

Hex-5-enopyranosides were prepared in an one-pot procedure from 6-bromo-6-deoxy- or 6-O-tosylhexopyranoside by the successive treatment with iodide anion and 1,8-diazabicycloundec-7-ene in DMSO.

SYNTHESIS OF TWO ENANTIOMERIC TETRASUBSTITUTED CYCLOHEXANONES FROM 6-DEOXYHEX-5-ENOPYRANOSIDE DERIVATIVES

The conversion of various 6-deoxyhex-5-enopyranoside derivatives in the presence of a catalytic amount of mercury(II) sulfate into chiral cyclohexanones has been studied.Under the experimental conditions used, the stereochemistry at position 5 of the tetr