82181-74-6

Basic information

• Product Name: N-trimethylsilyl-methylbis(dimethylaminophosphine) imine
• Synonyms: N-trimethylsilyl-methylbis(dimethylaminophosphine) imine
• CAS NO: 82181-74-6
• Molecular Weight: 221.358
• Mol File: 82181-74-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-trimethylsilyl-methylbis(dimethylaminophosphine) imine(CAS DataBase Reference)
• NIST Chemistry Reference: N-trimethylsilyl-methylbis(dimethylaminophosphine) imine(82181-74-6)
• EPA Substance Registry System: N-trimethylsilyl-methylbis(dimethylaminophosphine) imine(82181-74-6)

Safety Data

• Hazardous Substances Data: 82181-74-6(Hazardous Substances Data)

Upstream product

• 14937-39-4 methyl-bis(dimethylamino)phosphine 
• 4648-54-8 trimethylsilylazide 

Relevant articles and documents

SYNTHESIS AND NMR INVESTIGATION OF PHOSPHINEIMINOPHOSPHONIUM ORGANOFLUOROPHOSPHATE SALTS

The reaction of N-trimethylsilylphosphinineimines, Me3SiN=PR1R2R3 (R1, R2, and R3=hydrocarbon or NMe2 group) with the fluorophosphoranes, MePF4, PhPF4, and Me2PF3 has furnished fluorophosphineiminophosphonium organofluorophosphates, involving the anions, - (R=Me, Ph) or -, respectively.The characterization of these salts by 1H, 19F, and 31P n.m.r. spectroscopy is descriebed.The n.m.r. parameters are discussed in term of electronic structure.The 2JPP coupling constant was determined to be positive by triple resonance experiments on two of the compounds.