14937-39-4

Usage

InChI:InChI=1/C5H15N2P/c1-6(2)8(5)7(3)4/h1-5H3

Upstream product

• 1066-34-8 methyldibromophosphine 
• 124-40-3 dimethyl amine 
• 676-83-5 methyldichlorophosphane 
• 294-90-6 1,4,7,10-tetraazacyclododecan 
• 63366-54-1 bis[bis(dimethylamino)phosphinyl]methane 
• 91275-57-9 C₃₂H₃₆N₃O₅P 
• 3348-44-5 bis(N,N-dimethylamino)chlorophosphine 
• 75-16-1 methylmagnesium bromide 
• 917-54-4 methyllithium 

Downstream Products

• 38316-42-6 methylphosphonous acid diphenyl ester 
• 91282-69-8 C₄₀H₄₃N₄O₇P 
• 13463-40-6 iron pentacarbonyl 
• 87176-11-2 [bis(dimethylamino)methylphosphane]tetracarbonyliron 
• 185062-94-6 26,27-Dimethoxy-3,7,24-trimethyl-11,14,17,20-tetraoxa-2,4-diaza-3-phospha-tricyclo[20.3.1.1^5,9]heptacosa-1⁽²⁵⁾,5⁽²⁷⁾,6,8,22⁽²⁶⁾,23-hexaene 3-sulfide 
• 91275-57-9 C₃₂H₃₆N₃O₅P 
• 92208-94-1 (2R,4S,5R)-2,3,4-Trimethyl-5-phenyl-1,3,2-oxazaphospholidin 
• 92208-94-1 (2S,4S,5R)-2,3,4-Trimethyl-5-phenyl-1,3,2-oxazaphospholidin 
• 2083-91-2 N,N-Dimethyltrimethylsilylamine 
• 82181-74-6 N-trimethylsilyl-methylbis(dimethylaminophosphine) imine 
• 82181-79-1 C₁₁H₃₃N₅P₂Si 
• 52718-74-8 1,3-dibenzyl-2-methyl-[1,3,2]diazaphospholidine 
• 57602-61-6 2-(2-amino-phenoxy)-2-methyl-2,3-dihydro-2λ⁵-benzo[1,3,2]oxazaphosphole 
• 31641-50-6 C₁₂H₂₃N₃O₂P₂ 

Relevant academic research and scientific papers

Taking a bite of phosphorus: Unusual cleavage of a phosphorus-carbon bond

The diphosphine (Me2N)2PCH2P(NMe2)2 reacts with the tetraamino macrocycle cyclen at about 100°C in a closed system via cleavage of the P-C bond to yield cyclenphosphorane and bis(dimethylamino)methylphosphine. The presence of dimethylamine in this reaction is necessary, since a similar reaction which allows the amine to escape, produces an oligomeric product of formula [(C8H16N4)PCH2P]n.

SYNTHESIS OF DEOXYNUCLEOSIDE METHYLPHOSPHONATES VIA A PHOSPHONAMIDITE APPROACH

Deoxynucleoside methylphosphonamidites 1 have been synthesized as building monomers for the stepwise synthesis of methylphosphonate analogs of oligonucleotides.