82185-79-3

Upstream product

• 620-05-3 iodomethylbenzene 
• 63167-69-1 methyl 2,3-O-isopropylidene-α-D-mannopyranoside 
• 131089-35-5 methyl 6-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 150161-11-8 Methyl 4-O-benzyl-6-O-tert-butyldiphenylsilyl-2,3-di-O-isopropylidene-α-D-mannopyranoside 

Downstream Products

• 23477-56-7 methyl 4-O-benzyl-α-D-mannopyranoside 
• 161767-27-7 methyl-4-O-benzyl-6-deoxy-6-fluoro-2,3-O-isopropylidene-α-D-mannopyranoside 
• 740840-76-0 ethyl (methyl 4-O-benzyl-2,3-O-isopropylidene-6,7-dideoxy-α-D-manno-octo-6E-enopyranosid)uronate 
• 740840-78-2 ethyl (methyl 2,3-O-isopropylidene-6,7-dideoxy-4-phenylthionocarbonate-α-D-mannooctopyranosid)uronate 
• 740840-82-8 3'',4'',6''-tri-O-benzyl-1'',2''-dideoxy-D-arabino-hex-1''-enyl (methyl (4S)-4-C-((3',4',6'-tri-O-benzyl-1',2'-dideoxy-D-arabino-hex-1'-enyl)-(4-ethanoate))-2,3-O-isopropylidene-4,6,7-trideoxy-β-D-mannooctopyranosid)uronate 
• 316364-86-0 (3aS,4R,7R,8aR,8bR)-7-((3aS,4S,6S,7R,7aS)-7-Benzyloxy-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2,2-dimethyl-hexahydro-1,3,6-trioxa-5a-aza-as-indacen-4-ol 
• 316364-88-2 (3aR,4R,7R,7aS)-7-Acetoxy-4-[2-((3aS,4S,6R,7R,7aS)-7-benzyloxy-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-ethyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyridine-5-carboxylic acid benzyl ester 
• 316364-87-1 (3aR,4R,7R,7aS)-7-Acetoxy-4-[(R)-2-((3aS,4S,6R,7R,7aS)-7-benzyloxy-4-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-6-yl)-2-hydroxy-ethyl]-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyridine-5-carboxylic acid benzyl ester 
• 132032-79-2 methyl 6-O-<2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl>-4-O-benzyl-7,8-dideoxy-2,3-O-isopropylidene-α-D-manno-oct-7-enopyranoside 
• 132032-82-7 methyl 6-O-<2,3:4,6-di-O-isopropylidene-α-D-mannopyranosyl>-4-O-benzyl-7,8-dideoxy-2,3-O-isopropylidene-α-D-manno-oct-7-enopyranoside 
• 132032-80-5 methyl 4,6-di-O-benzyl-2,3-O-isopropylidene-L-glycero-α-D-manno-heptopyranoside 
• 132032-77-0 methyl 4,6-di-O-benzyl-7,8-dideoxy-2,3-O-isopropylidene-α-D-manno-oct-7-enopyranoside 
• 132032-78-1 methyl 6-O-acetyl-4-O-benzyl-7,8-dideoxy-2,3-O-isopropylidene-α-D-manno-oct-7-enopyranoside 
• 132032-61-2 (3S,4R,5S,6R)-5-Benzyloxy-6-((S)-1-benzyloxy-2-hydroxy-ethyl)-tetrahydro-pyran-2,3,4-triol 

Relevant academic research and scientific papers

A double ring-closing metathesis approach for the synthesis of β-C-trisaccharides

Good things come in threes: A variety of β-C-trisaccharides have been successfully synthesized by double ring-closing metathesis, which provides the products in excellent overall yield after functionalization of the newly formed double bonds (see scheme).

Synthesis of Tethered Trisaccharides to Probe Inter-Saccharide Flexibility in Carbohydrate - Protein Interactions

Two crystal structures of the trisaccharide epitope α-D-Galp(1→2)[α-D-Abep(1→3)α-D-Manp1→OCH 3 1 bound to antibody Fab and single-chain Fv fragments have been used to guide the design of an intramolecular tether that constrains the trisaccharid

Synthesis of 4-nitrophenyl O-(2-acetamido-2-deoxy-β-D-glucopyranosyl)-(1->2)-O-(6-O-methyl-α-D-mannopyranosyl)-(1->6)-β-D-glucopyranoside and its 4',6'-di-O-methyl analog. Potential inhibitors of N-acetylglucosaminyltransferase V (GnT-V)

O-(2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1->2)-3,4-di-O-acetyl-6-O-methyl-α-D-mannopyranosyl bromide and O-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranosyl)-(1->2)-3-O-acetyl-4,6-di-O-methyl-α-D-mannopyranosyl bromide were