82202-13-9Relevant academic research and scientific papers
Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes with PCC
Wu, Xia,Lei, Jian,Song, Zhen Lei
experimental part, p. 306 - 309 (2012/01/14)
An oxidative rearrangement of cyclic tertiary α-hydroxy allylsilanes has been carried out in refluxing ClCH2CH2Cl with pyridinium chlorochromate (PCC). The reaction provides a convenient method to synthesize cyclic β-silylenones in m
Silicon-induced ene-type reaction in the thermal conversion of enolates to ss-silyl enones with molecular dioxygen
Hwu, Jih Ru,Chen, Chien Hsien,Hsu, Chuan-I.,Das, Asish R.,Li, Yen Cheng,Lin, Lung Ching
supporting information; experimental part, p. 1913 - 1916 (2009/04/18)
Reaction of alkyl, acetoxy, and silyl enol ethers of 3-(organosilyl) cyclohexanone with molecular dioxygen in toluene at 110 °C produced the corresponding conjugated enones in yields up to 88% yield. The reaction of the same type failed on replacement of
THE SYNTHESIS OF αβ-UNSATURATED KETONES FROM β-SILYLENONES AND β-SILYLYNONES
Fleming, Ian,Perry, David A.
, p. 4027 - 4034 (2007/10/02)
Conjugate addition, followed by alkylation, bromination and desilyl-bromination make the β-silylketone (4) an a3d2-synthon (5) and the β-silylynone (6) a 2a3d2-synthon (7).
