104066-67-3Relevant articles and documents
CHEMICAL AND SPECTROSCOPIC INVESTIGATIONS OF TRIALKYLSILYLCUPRATES DERIVED FROM CuCN.
Sharma, Sunaina,Oehlschlager, Allan C.
, p. 557 - 568 (1989)
We disclose that in THF addition of increasing amounts of ΦMe2SiLi (with LiCl) to CuCN gives sequentially ΦMe2SiCu(CN)Li (1:1), (ΦMe2Si)2Cu(CN)Li2 (2:1) and (ΦMe2Si)3CuLi2 (3:1).The formation of the latter species is corroborated with chemical tests on bo
TRANSITION-METAL CATALYZED SILYLZINCATION AND SILYLALUMINATION OF ACETYLENIC COMPOUNDS
Wakamatsu, Kuni,Nonaka, Tsuyoshi,Okuda, Yasuhiro,Tueckmantel, Werner,Oshima, Koichiro,et al.
, p. 4427 - 4436 (2007/10/02)
Dialkyl(dimethylphenylsilyl)zinclithium and trialkyl(dimethylphenylsilyl)aluminiumlithium add effectively to internal acetylenes as well as terminal ones in the presence of transition-metal catalysts to provide vinylsilanes with high stereo- and regiosele