82204-76-0

Upstream product

• 917-64-6 methyl magnesium iodide 
• 6575-13-9 2,6-dimethylbenzonitrile 
• 576-22-7 2-Bromo-m-xylene 
• 75-05-8 acetonitrile 

Downstream Products

• 2633-42-3 2-bromo-2',6'-dimethylacetophenone 
• 74331-78-5 α-(2,6-dimethylphenyl)vinyl bromide 
• 2142-76-9 2',6'-dimethylacetophenone 

Relevant academic research and scientific papers

Study of the reactivity of organonickel sigma-complexes towards nitriles

The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2′-bipyridine, towards nitriles (acetonitr

Alkenyl bromides by brominative deoxygenation of ketones in one or two steps

The conversion of ketones into alkenyl bromides is accomplished in one or two steps by 2,2,2-tribromo-2,2-dihydro-1,3,2-benzodioxaphosphole or by the dibromomethyl methyl ether prepared therefrom. Investigations of the scope and limitations provide some hints for the preparative planning and improvement.