82238-14-0

Upstream product

• 77896-99-2 2-<(Z)-3-(1-methoxy-1-methylethoxy)-2-propenyl>-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 100-52-7 benzaldehyde 

Downstream Products

• 13995-41-0 4,5-trans-2,2-dimethyl-4-phenyl-5-ethenyl-1,3-dioxolane 
• 13995-41-0 4,5-cis-2,2-dimethyl-4-phenyl-5-ethenyl-1,3-dioxolane 

Relevant academic research and scientific papers

Stereoselective Synthesis of Alcohols, XX. - Diastereoselective Addition of γ-Alkoxyallylboronates to Aldehydes

Both the (Z)- and (E)-γ-alkoxysubstituted allylboronates 1 and 3 have been prepared.They add to aldehydes with a diastereoselectivity generally exceeding 90percent to give the syn-(2) and anti-diol derivatives 4, respectively.The structure of one of these adducts has been established by conversion into exo-brevicomin (26).