82238-33-3Relevant academic research and scientific papers
CHEMISTRY OF CIS- AND TRANS-9-PHENYLSELENOXANTHENE-N-ARYLSULFONYLSELENILIMINES
Tomimatsu, Kiminori,Kataoka, Tadashi,Shimizu, Hiroshi,Hori, Mikio
, p. 97 - 110 (2007/10/02)
cis- and trans-9-Phenylselenoxanthene-N-(arylsulfonyl)selenilimines were synthesized and isolated.Their stereochemistry was ascertained from the NMR spectra.Cis isomers reacted with chloramine-T or -B by an SN2 type substitution to form trans i
STEREOISOMERS OF SELENILIMINES: ISOLATION AND REACTIONS OF 9-PHENYLSELENOXANTHENE-N-ARYLSULFONYLSELENILIMINES
Hori, Mikio,Kataoka, Tadashi,Shimizu, Hiroshi,Tomimatsu, Kiminori
, p. 901 - 904 (2007/10/02)
The isolated cis- and trans-9-phenylselenoxanthene-N-arylsulfonylselenilimines were not interconverted thermally. cis-Isomers were converted to trans-isomers by chloramine-T or -B in a fashion of SN2 type substitution. cis-Isomers did not rearrange but trans-isomers rearranged thermally to 9-arylsulfonamido-9-phenylselenoxanthenes, whereas both isomers underwent the base-catalyzed intermolecular rearrangement.
