82246-91-1

Basic information

• Product Name: (4bS,8S,8aR)-3-methoxy-8-(methoxycarbonyl)-4b,8-dimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthrene-2-carboxylic acid
• Synonyms: (4bS,8S,8aR)-3-methoxy-8-(methoxycarbonyl)-4b,8-dimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthrene-2-carboxylic acid
• CAS NO: 82246-91-1
• Molecular Weight: 346.423
• Mol File: 82246-91-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4bS,8S,8aR)-3-methoxy-8-(methoxycarbonyl)-4b,8-dimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthrene-2-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (4bS,8S,8aR)-3-methoxy-8-(methoxycarbonyl)-4b,8-dimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthrene-2-carboxylic acid(82246-91-1)
• EPA Substance Registry System: (4bS,8S,8aR)-3-methoxy-8-(methoxycarbonyl)-4b,8-dimethyl-4b,5,6,7,8,8a,9,10-octahydrophenanthrene-2-carboxylic acid(82246-91-1)

Safety Data

• Hazardous Substances Data: 82246-91-1(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 22489-68-5 methyl 13-bromo-12-methoxypodocarpa-8,11,13-trien-19-oate 

Downstream Products

• 138055-96-6 methyl 13-12-methoxypodocarpa-8,11,13-triene-19-oate 
• 138055-94-4 methyl 13-<(N,N'-dicyclohexylureido)carbonyl>-12-methoxypodocarpa-8,11,13-triene-19-oate 

Relevant articles and documents

Directed ortho Metallation Studies on Podocarpic Acid Derivatives: Advantageous Use of a LICKOR Base

Methyl 13-(N,N-diethylcarbamoyl)-12-methoxypodocarpa-8,11,13-trien-19-oate (2), 13-(N,N-diethylcarbamoyl)-12,19-dimethoxypodocarpa-8,11,13-triene (8) and N,N-diethyl-2-methoxy-4,5-dimethylbenzamide (15) were prepared for studies involving lithiation directed ortho to the tertiary amide group, in which the use of a LICKOR base was advantageous.Some dynamic features of the n.m.r. spectra of the amides are discussed.Oxazoline derivatives of both the monocyclic and diterpenoid compounds were synthesized.