82268-86-8Relevant articles and documents
REACTIONS INVOLVING TRANSITION METALS. XIX. SOME REACTIONS OF PERFLUORONORBORNADIENE WITH LOW VALENT TRANSITION METAL COMPLEXES
Booth, Brian L.,Casey, Sylvia,Haszeldine, Robert N.
, p. 289 - 300 (1982)
Perfluoronorbornadiene reacts with the compounds to give the adducts and in which one of the double bonds is coordinated to the metal atom.The platinum complex reacts further with to give 2> having both double bonds coordinated to a Pt atom.The carbonylmetal anions -> react to form the mono-substitution products (M = Mn(CO)5, Re(CO)5, Ir(CO)2(PPh3)2, Rh(CO)2(PPh3)2, but the use of an excess of - leads to substitution of one fluorine atom on each of the double bonds.The complex having M = Mn(CO)5 reacts with to afford the derivative >, and the compound where M = Ir(CO)2(PPh3)2 undergoes an oxidative addition reaction with acetyl chloride.Oxidative coupling products have been isolated on UV irradiation of a mixture of perfluoronorbornadiene and 4-CH2=CRCH=CH2)(CO)3> (R = H, Me), and under similar conditions the reaction with Fe(CO)5 affords in very low yield.
