82292-83-9

Upstream product

• 2071-20-7 bis-diphenylphosphinomethane 
• 82621-40-7 (CO)4ReHCHCHC₄H₉Re(CO)4 

Downstream Products

• 94111-33-8 Cl(CO)4Re(C₆H₅)2PCH₂P(C₆H₅)2Re(CO)4Cl 
• 94111-34-9 Re₂(C₆H₅)2PCH₂P(C₆H₅)2(CO)6Cl₂ 
• 95648-63-8 Re₂(CO)6((C₆H₅)2PCH₂P(C₆H₅)2)2 
• 94111-32-7 Re₂(CO)7(P(C₆H₅)3)((C₆H₅)2PCH₂P(C₆H₅)2) 
• 94111-31-6 Re₂(CO)7(P(CH₃)3)((C₆H₅)2PCH₂P(C₆H₅)2) 
• 88271-79-8 (μ-H)(μ-OH)Re2(CO)6(bis(diphenylphosphino)methane) 
• 88271-80-1 (μ-OH)2Re2(CO)6(bis(diphenylphosphino)methane) 
• 94136-27-3 Re₂(CO)7(NCCH₃)((C₆H₅)2PCH₂P(C₆H₅)2) 
• 94090-57-0 μ-hydrido-dirhenium(carbonyl)7(μ-dppm)(η1-C2C6H5) 
• 94111-25-8 μ-hydrido-dirhenium(carbonyl)6(μ-dppm)(μ-η1,η2-C2C6H5) 
• 94136-24-0 dirhenium(carbonyl)5(dppm)(μ-η1,η2-C(C6H5)CH2)(μ-η1,η2-CCPh) 

Relevant academic research and scientific papers

Stabilization of the bis(diphenylphosphino)methanide ion by bridging dirhenium octacarbonyl:

The anion of (1) is formed cleanly by treatment of Re2(CO)8(Ph2PCH2PPh2) with LiAlH4 in tetrahydrofuran (56percent yield).Anion 1 is remarkably stable toward all organic electrophiles examined.Whereas protons are added and

Photolysis of Re2(CO)10 in the Presence of Simple Olefins. Thermal Reactivity of (μ-Hydrido)(μ-alkenyl)dirhenium Octacarbonyl Compounds

Photolysis of Re2(CO)10 at 25 oC in the presence of ethylene, terminal olefins, or 2-butene results in formation of (μ-hydrido)(μ-alkenyl)dirhenium octacarbonyl complexes in high yield.The bridging alkenyl ligand forms a ? bond to one Re and a