Stabilization of the bis(diphenylphosphino)methanide ion by bridging dirhenium octacarbonyl:

DOI: 10.1016/0022-328X(80)83016-6

Source and publish data:

Journal of Organometallic Chemistry p. C7 - C10 (1988)

Update date:2022-08-17

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Authors:

Dominguez, Raul

Lynch, Thomas J.

Wang, Fei

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Article abstract of DOI:10.1016/0022-328X(80)83016-6

The anion of (1) is formed cleanly by treatment of Re2(CO)8(Ph2PCH2PPh2) with LiAlH4 in tetrahydrofuran (56percent yield).Anion 1 is remarkably stable toward all organic electrophiles examined.Whereas protons are added and

Full text of DOI:10.1016/0022-328X(80)83016-6

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Article Doi

Stabilization of the bis(diphenylphosphino)methanide ion by bridging dirhenium octacarbonyl:

DOI: 10.1016/0022-328X(80)83016-6

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0022-328X(80)83016-6

Full text of DOI:10.1016/0022-328X(80)83016-6

Products guided by the article

R&D Labs maybe for 82292-83-9

Relevant to this article

Preparation of optically active 1-aminoalkylphosphonic acids from chiral carbamates and chiral ureas

Insertion of Diphenylacetylene into Rh-Hydride and Rh-Boryl Bonds: Influence of the Boryl on the Behavior of the β-Borylalkenyl Ligand

N-heterocyclic carbene palladium(II)-catalyzed Suzuki-Miyaura cross coupling of N-acylsuccinimides by C-N cleavage

Reactivity of an α-Acyl-α-cyclopropyl-carbenium Ion: a Highly Stereoselective Cyclopropylmethyl-Cyclopropylmethyl Rearrangement