Stabilization of the bis(diphenylphosphino)methanide ion by bridging dirhenium octacarbonyl:

DOI: 10.1016/0022-328X(80)83016-6

Source and publish data:

Journal of Organometallic Chemistry p. C7 - C10 (1988)

Update date:2022-08-17

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Authors:

Dominguez, Raul

Lynch, Thomas J.

Wang, Fei

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Article abstract of DOI:10.1016/0022-328X(80)83016-6

The anion of (1) is formed cleanly by treatment of Re2(CO)8(Ph2PCH2PPh2) with LiAlH4 in tetrahydrofuran (56percent yield).Anion 1 is remarkably stable toward all organic electrophiles examined.Whereas protons are added and

Full text of DOI:10.1016/0022-328X(80)83016-6

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