82297-10-7Relevant academic research and scientific papers
CAPTO-DATIVE SUBSTITUENT EFFECTS. 12 -NEW KETENE EQUIVALENTS FOR DIELS-ALDER CYCLOADDTIONS
Stella, Lucien,Boucher, Jean-Luc
, p. 953 - 956 (1982)
We describe the use of "capto-dative" olefins 1 as novel ketene equivalents which behave as efficient dienophiles in the Diels-Alder process.
DIENOPHILIE DES OLEFINES CAPTODATIVES: CYCLOADDITIONS DE DIELS-ALDER DE L'α-METHYLTHIO-ACRYLONITRILE ET TRANSFORMATION DES ADDUITS
Boucher, Jean-Luc,Stella, Lucien
, p. 3871 - 3886 (2007/10/02)
The cycloaddition reactions of the α-methylthio-acrylonitrile with 1,3-dienes are investigated.The uncatalyzed thermal reactions proceed in high yields very stereoselectively with cyclic dienes and especially even room temperature with cyclopentadiene.In
