82315-88-6Relevant articles and documents
Highly efficient Narasaka-Heck cyclizations mediated by P(3,5-(CF 3)2C6H3)3: Facile access to N-heterobicyclic scaffolds
Faulkner, Adele,Bower, John F.
, p. 1675 - 1679 (2012/04/05)
N-heterobicyclic scaffolds: Highly efficient palladium-catalyzed cyclizations of oxime esters with cyclic alkenes were used as a general entry to perhydroindole and related scaffolds. The chemistry is reliant upon the use of P(3,5-(CF3)2/
Regioselective Lewis Acid-mediated α-sec-Alkylation of Carbonyl Compounds
Reetz, Manfred T.,Walz, Peter,Huebner, Friedhelm,Huettenhain, Stefan H.,Heimbach, Horst,Schwellnus, Konrad
, p. 322 - 335 (2007/10/02)
Carbonyl compounds such as ketones, aldehydes, acyloins, or carboxylic esters can be alkylated at the α-position via the corresponding O-silylated forms using activated alkyl halides or acetates in the presence of Lewis acids.In the case of unsymmetricall