82335-20-4Relevant academic research and scientific papers
Facile access to the ABC ring system of the taxane diterpenes via anionic oxy-cope rearrangements
Martin,Assercq,Austin,Dantanarayana,Fishpaugh,Gluchowski,Guinn,Hartmann,Tanaka,Wagner,White
, p. 3455 - 3482 (2007/10/02)
The anionic oxy-Cope rearrangement of bicyclo[2.2.2]octadienols serves as a key step for the construction of substituted bicyclo[5.3.1]undecenones and provides a novel entry to the AB ring system of the taxane diterpenes. The bicyclo[2.2.2]octadienols 11a
Alkoxide-Accelerated Sigmatropic Rearrangements. A Novel Entry to the Bicycloundec-7-ene System of the Taxane Diterpenes
Martin, Stephen F.,White, James B.,Wagner, Rolf
, p. 3190 - 3192 (2007/10/02)
An anionic oxy-Cope rearrangement serves as the key step in a novel route to the bicycloundec-7-ene ring system, which is an important structural element of the taxane diterpenes.
