930-66-5

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 101, p. 228, 1979 DOI: 10.1021/ja00495a043

InChI:InChI=1/C6H9Cl/c7-6-4-2-1-3-5-6/h4H,1-3,5H2

Upstream product

• 91-22-5 quinoline 
• 19043-36-8 (+/-)-1r,2t-dibromo-1-chloro-cyclohexane 
• 108-94-1 cyclohexanone 
• 17497-53-9 1-iodo-1-cyclohexene 
• 23904-34-9 (1-Iodomethylene)cyclopentane 
• 13898-96-9 (+-)-trans-1-bromo-2-chloro-cyclohexane 
• 33815-66-6 trans-2-chlorocyclohexyl acetate 
• 131195-46-5 trans-2-chlorocyclohexyl vinyl ether 
• 507-40-4 tert-butylhypochlorite 
• 110-83-8 cyclohexene 
• 64-17-5 ethanol 
• 10498-35-8 cis-1,2-dichloro-cyclohexane 
• 123-91-1 1,4-dioxane 
• 40099-06-7 1,6-dichlorocyclohexene 

Downstream Products

• 17874-17-8 cyclohex-1-enyl-trimethyl-silane 
• 51595-54-1 1-Chlor-7-oxa-bicyclo<4.1.0>heptan 
• 5682-75-7 3-chloro-2-cyclohexenone 
• 3400-88-2 2-chlorocyclohex-2-en-1-one 
• 100877-65-4 4-cyclohex-1-enyl-1,2,5-trimethyl-piperidin-4-ol 
• 32617-36-0 1-bromo-1-chloro-cyclohexane 
• 4845-04-9 1-cyclohexene-1-methanol 
• 371-90-4 1,1-difluorocyclohexane 
• 371-89-1 chlorofluorocyclohexane 
• 2108-92-1 1,1-dichlrocyclohexane 
• 19024-48-7 1,1,2-trichlorocyclohexane 
• 87-82-1 hexabromobenzene 
• 67820-31-9 acetoxy-2-chlorocyclohex-2-ene 
• 40099-06-7 1,6-dichlorocyclohexene 

Relevant academic research and scientific papers

Cyclohexeno[3,4]cyclodec-1,5-diyne-3-ene: A Convenient Enediyne

Enediynes are widely studied to understand their cycloaromatization and the trapping of the resulting p-dehydrobenzene diradical. However, few model substrates are known, and they are hard to synthesize and difficult to handle. Herein we report cyclohexen

Preparation method of heteroatom-containing cyclohexene halide

The invention discloses a preparation method of a heteroatom-containing cyclohexene halide, belonging to the field of synthesis of fine chemical intermediates. According to the preparation method, cyclohexanone containing heteroatoms is used as a raw material, and gem-dihalide or alkenyl halide is mainly generated in a halogenating reagent; and after an additive is added into organic alkali, and hydrogen halide is removed to generate cyclohexene halide containing heteroatoms. The method is simple in process; the operation of purifying a mixture in traditional methods is avoided; and a productis fully utilized. Under close-to-elimination condition of gem-dibromide, an additive is added to overcome the problem of difficulties in gem-dichloride elimination is by adding, and the purpose of controlling regioselectivity is achieved through steric hindrance of different alkalis.

Synthesis of Vinyl Chlorides via Triphosgene-Pyridine Activation of Ketones

Herein, we describe a mild method to prepare aliphatic and aromatic vinyl chlorides from their corresponding ketones via triphosgene-pyridine activation in dichloromethane at reflux. The mechanism of this reaction is proposed to involve formation of a put

The continuous reaction device and method of using the continuous composite (by machine translation)

PROBLEM TO BE SOLVED: compounds with high productivity can be generated. SOLUTION: 1 the raw material supply section 12 and a first, a second and 2 the raw material supply section 14, and a reaction part 18, the first reaction part 1 from the raw material supply section 1 and a second quantity of raw material, the raw material supply section 2 from the first reaction part 2 and a second quantity of raw material, the raw material supply section 1 from the first reaction part 1 and a second temperature of the raw material, the raw material supply section 2 from the first reaction part 2 and supplied to the temperature of the raw material, and having a control part 22, a continuous reaction device as shown in the drawing. Selected drawing: fig. 1 (by machine translation)

Structure and Dynamic Features of an Intramolecular Frustrated Lewis Pair

Di(mesityl)cyclohexenylphosphine undergoes hydroboration with Piers' borane [HB(C6F5)2] to yield the cyclohexylene- anellated frustrated Lewis pair 5. This P/B pair splits H2 with the formation of the product 4

First catalytic and green synthesis of aryl-(Z)-vinyl chlorides and its plausible addition-elimination mechanism

(Chemical Equation Presented) Via a catalytic cycle in the presence of scandium triflate (2 mol %)/DMF (1 mol %)/benzoyl chloride (5 mol %), aromatic ketones were treated with bis(trichloromethyl) carbonate (BTC) to afford aryl-(Z)-vinyl chlorides. All metal triflates tested in the reaction showed highly catalytic activity. A plausible addition-elimination mechanism was proposed. The present work describes the first catalytic and green route to the synthesis of aryl-(Z)-vinyl chlorides.

Method for chlorinating ketones

In a process for chlorinating ketones which, apart from the carbonyl group, are inert in respect of triarylphosphine dichlorides, except for cyclopropyl methyl ketone, in which the ketones are reacted with a chlorinating agent in the presence of triarylphosphine oxides, the amount of triarylphosphine oxide is from 0.1 to 10 mol %, based on the amount of ketone. The ketones preferably have a least one CH-acid proton in the α position to the carbonyl group.

Dichotomous reactivity of PCl5 and PBr5 toward cyclic ketones: A one-step preparation of 1,1,2-trichlorocycloalkanes

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