82343-62-2

Upstream product

• 34164-50-6 4-penten-1-ylmagnesium bromide 
• 474094-60-5 (S)-(-)-3,4-dimethyl-2-cyclohexen-1-one 
• 79-22-1 methyl chloroformate 
• 10463-42-0 3,4-dimethyl-cyclohex-2-enone 
• 1119-51-3 bromopentene 

Downstream Products

• 82343-63-3 Carbonic acid (3S,4R)-3,4-dimethyl-3-(3-oxiranyl-propyl)-cyclohex-1-enyl ester methyl ester 
• 82343-65-5 Carbonic acid (3R,4S)-3,4-dimethyl-3-(4-oxo-butyl)-cyclohex-1-enyl ester methyl ester 
• 87011-65-2 methyl (trans-3,4-dimethoxybutyl-3-(4-pentenyl)-1-cyclohexen-1-yl)-carbonate 
• 82343-65-5 Carbonic acid (3S,4R)-3,4-dimethyl-3-(4-oxo-butyl)-cyclohex-1-enyl ester methyl ester 
• 87011-67-4 <(1α,6β)-2-<(dimethylamino)methyl>-1,6-dimethyl-3-oxo-cyclohexanyl>butanal 
• 87011-66-3 (3R,4S)-3-(4,4-Dimethoxy-butyl)-2-dimethylaminomethyl-3,4-dimethyl-cyclohexanone 
• 87011-69-6 methyl 2-bromo-6-<(1α,6β)-1,6-dimethyl-3-oxo-cyclohexyl>-2-hexenoate 
• 87011-68-5 methyl 2-bromo-6-<(1α,6β)-2-<(dimethylamino)methyl>-1,6-dimethyl-3-oxo-cyclohexyl>-2-hexenoate 
• 82343-67-7 (E)-6-((1R,6S)-3-Methoxycarbonyloxy-1,6-dimethyl-cyclohex-2-enyl)-hex-2-enoic acid methyl ester 
• 82343-66-6 (3R,4S)-3,4-Dimethyl-2-methylene-3-(3-oxiranyl-propyl)-cyclohexanone 

Relevant academic research and scientific papers

A Stereospecific 2 + 2 + 2 Annulation

A mew strategy for multiple annulation involving sequential Michael and Aldol reactions is described.

ENOL CARBONATES: WEAKLY NUCLEOPHILIC PRECURSORS OF SITE-SPECIFIC ENOLATES

Examples of trapping of site-specific enolates by enol methoxycarbonylation are described.Selective operations at a remote double bond in the presence of the enol carbonate functionality have been realized.Site-specific enolates can be retrieved from the